The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero‐Valent Lead Complex (“Plumbylone”)
The elusive plumbylone {[Si(II)(Xant)Si(II)]Pb(0)} 3 stabilized by the bis(silylene)xanthene chelating ligand 1, [Si(II)(Xant)Si(II)=PhC(NtBu)(2)Si(Xant)Si(NtBu)(2)CPh], and its isolable carbonyl iron complex {[Si(II)(Xant)Si(II)]Pb(0)Fe(CO)(4)} 4 are reported. The compounds 3 and 4 were obtained st...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545849/ https://www.ncbi.nlm.nih.gov/pubmed/35848899 http://dx.doi.org/10.1002/anie.202209442 |