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The concise synthesis and resolution of planar chiral [2.2]paracyclophane oxazolines by C–H activation

Planar chiral [2.2]paracyclophanes are resolved through the direct C–H arylation of enantiopure oxazolines, providing a convenient route to ligands and chiral materials. Preliminary results show that hydrolysis followed by decarboxylative phosphorylation leads to enantiopure [2.2]paracyclophane deri...

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Detalles Bibliográficos
Autores principales: Tewari, Shashank, Mungalpara, Maulik N., Patel, Suraj, Rowlands, Gareth J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8984818/
https://www.ncbi.nlm.nih.gov/pubmed/35424822
http://dx.doi.org/10.1039/d2ra01075e