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Inducing Nucleophilic Reactivity at Beryllium with an Aluminyl Ligand

[Image: see text] The reactions of anionic aluminium or gallium nucleophiles {K[E(NON)]}(2) (E = Al, 1; Ga, 2; NON = 4,5-bis(2,6-diisopropylanilido)-2,7-ditert-butyl-9,9-dimethylxanthene) with beryllocene (BeCp(2)) led to the displacement of one cyclopentadienyl ligand at beryllium and the formation...

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Detalles Bibliográficos
Autores principales: Boronski, Josef T., Thomas-Hargreaves, Lewis R., Ellwanger, Mathias A., Crumpton, Agamemnon E., Hicks, Jamie, Bekiş, Deniz F., Aldridge, Simon, Buchner, Magnus R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9983009/
https://www.ncbi.nlm.nih.gov/pubmed/36786728
http://dx.doi.org/10.1021/jacs.3c00480