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Reversible reduction drives anion ejection and C(60) binding within an Fe(II)(4)L(6) cage

Fe(II)(4)L(6) tetrahedral cage 1 was prepared from a redox-active dicationic naphthalenediimide (NDI) ligand. The +20 charge of the cage makes it a good host for anionic guests, with no binding observed for neutral aromatic molecules. Following reduction by Cp(2)Co, the cage released anionic guests;...

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Detalles Bibliográficos
Autores principales:	Lu, Zhenpin, Ronson, Tanya K., Nitschke, Jonathan R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8146419/ https://www.ncbi.nlm.nih.gov/pubmed/34084365 http://dx.doi.org/10.1039/c9sc05728e

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