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Mechanism of Phosphine-Catalyzed Novel Rearrangement of Vinylcyclopropylketone to Cycloheptenone: A DFT Study

[Image: see text] The title reaction is theoretically investigated in detail using density functional theory. Three possible routes starting from keto- or enol-type vinylcyclopropylketone are considered in this work. Results indicate that phosphine catalyst would first attack at the three-membered r...

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Detalles Bibliográficos
Autores principales: Wu, Yong, Li, Mingzhen, Jin, Lu, Zhao, Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7034002/
https://www.ncbi.nlm.nih.gov/pubmed/32095718
http://dx.doi.org/10.1021/acsomega.9b03902

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