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Pre-electrolysis of LiClO(4) in Acetonitrile: Electrochemically Induced Protolytic Carbon–Carbon Bond Formation of Benzylic Ethers and Acetals with Allyl Trimethylsilane and Other Carbon Nucleophiles
[Image: see text] The pre-electrolysis of LiClO(4) in acetonitrile in an undivided cell applying only “catalytic” amounts of current (e.g., 0.05 F) led to the formation of a strong acidic medium for the activation of benzylic ethers and acetals. The activated primary and secondary benzylic ethers an...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10476155/ https://www.ncbi.nlm.nih.gov/pubmed/37594465 http://dx.doi.org/10.1021/acs.joc.3c01256 |